Here's a clean way to compare $2^x$ and $x^2$ for real $x$.
For $x \neq 0$,
Because $\ln$ is strictly increasing,
$\;2^x > x^2 \iff F(x)>0$, $\;2^x = x^2 \iff F(x)=0$, $\;2^x < x^2 \iff F(x)<0$.
Thus $F$ is:
with $2/\ln 2\approx 2.885$. Also $F(x)\to+\infty$ as $x\to 0^\pm$, and $F(x)\to -\infty$ as $x\to -\infty$.
Obvious solutions: $x=2$ and $x=4$ (since $2^2=4=2^2$ and $2^4=16=4^2$).
On $(0,\infty)$, the behavior above implies these are the only positive solutions, with $F$ dipping below 0 between them.
On $(-\infty,0)$, monotonicity gives exactly one negative solution, found numerically (e.g., Newton's method on $f(x)=2^x-x^2$, $f'(x)=2^x\ln2-2x$) at
결론:
converges to $-0.7666646959\ldots$ in a few steps.